Semiconductor device and manufacturing method thereof

ABSTRACT

A semiconductor device includes an isolation insulating layer disposed over a substrate, a fin structure disposed over the substrate, and extending in a first direction in plan view, an upper portion of the fin structure being exposed from the isolation insulating layer, a gate structure disposed over a part of the fin structure, the gate structure extending in a second direction crossing the first direction, and a source/drain structure formed on the upper portion of the fin structure, which is not covered by the gate structure and exposed from the isolation insulating layer. The source/drain structure includes a SiP layer, and an upper portion of the source/drain structure includes an alloy layer of Si, Ge and Ti.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a Divisional application of U.S. patent application Ser. No. 15/382,921 filed on Dec. 19, 2016, which claims priority to U.S. Provisional Patent Application 62/296,957 filed Feb. 18, 2016, the entire disclosure of each of which is incorporated herein by reference.

TECHNICAL FIELD

The disclosure relates to a semiconductor integrated circuit, and more particularly to a semiconductor device having a uniform and thin silicide layer on an epitaxial source/drain (S/D) structure and its manufacturing process.

BACKGROUND

As the semiconductor industry has progressed into nanometer technology process nodes in pursuit of higher device density, higher performance, and lower costs, challenges from both fabrication and design issues have resulted in the development of three-dimensional designs, such as a fin field effect transistor (Fin FET) and the use of a metal gate structure with a high-k (dielectric constant) material. The metal gate structure is often manufactured by using gate replacement technologies, and sources and drains are formed by using an epitaxial growth method. Further, a silicide layer is formed on the sources and drains.

BRIEF DESCRIPTION OF THE DRAWINGS

The present disclosure is best understood from the following detailed description when read with the accompanying figures. It is emphasized that, in accordance with the standard practice in the industry, various features are not drawn to scale and are used for illustration purposes only. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.

FIGS. 1A-1C show an exemplary sequential process flow according to one embodiment of the present disclosure.

FIGS. 2-16 show exemplary cross sectional views of various stages for manufacturing a Fin FET device according to one embodiment of the present disclosure.

FIGS. 17-21 show exemplary cross sectional views of various stages for manufacturing a Fin FET device according to another embodiment of the present disclosure.

DETAILED DESCRIPTION

It is to be understood that the following disclosure provides many different embodiments, or examples, for implementing different features of the invention. Specific embodiments or examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, dimensions of elements are not limited to the disclosed range or values, but may depend upon process conditions and/or desired properties of the device. Moreover, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed interposing the first and second features, such that the first and second features may not be in direct contact. Various features may be arbitrarily drawn in different scales for simplicity and clarity. In the accompanying drawings, some layers/features may be omitted for simplification.

Further, spatially relative terms, such as “beneath,” “below,” “lower,” “above,” “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly. In addition, the term “made of” may mean either “comprising” or “consisting of.” Further, in the following fabrication process, there may be one or more additional operations in/between the described operations, and the order of operations may be changed.

FIGS. 1A-1C show exemplary sequential process flow for forming a silicide layer according to one embodiment of the present disclosure.

As shown in FIG. 1A, a first layer 2 containing Si_(1-x)Ge_(x) doped with phosphorous (P) (hereinafter referred to as SiGe:P) is formed by an epitaxial deposition process over an n-type semiconductor layer 1. The n-type semiconductor layer 1 includes heavily doped n-type Si based semiconductor materials. The n-type semiconductor layer 1 includes SiP or SiCP. In this embodiment, SiP is used.

An amount of P in the SiP layer is in a range from about 1×10²⁰ cm⁻³ to about 5×10²¹ cm⁻³ in some embodiments. In certain embodiments, the SiP layer includes two or more SiP layers with different P amounts.

The fraction x of Ge in the SiGe:P first layer 2 is in a range from about 0.25 to about 0.50 in some embodiments, and is in a range from about 0.30 to about 0.40 in other embodiments. An amount of phosphorous in the SiGe:P first layer 2 is in a range from about 1×10²⁰ cm⁻³ to about 5×10²¹ cm⁻³ in some embodiments, and in in a range from about 5×10²⁰ cm⁻³ to about 1×10²¹ cm⁻³ in other embodiments.

The thickness of the first SiGe:P layer 2 is in a range from about 1 nm to about 20 nm in some embodiments, and is in a range from about 5 nm to about 10 nm in other embodiments.

The first SiGe:P layer is epitaxially formed and thus has a crystal structure. In certain embodiments, the first SiGe:P layer has a polycrystalline or an amorphous structure.

Then, as shown in FIG. 1B, a second layer 3 containing a metal material is formed over the first SiGe layer 2. The metal material for the second layer 3 is at least one of Ti, Co, Ni, W or Ta. In one embodiment, Ti is used for the second layer 3. Two or more layers of metal material may be used for the second layer 3. The thickness of the second layer 3 is in a range from about 1 nm to about 15 nm in some embodiments, and is in a range from about 3 nm to about 10 nm in other embodiments.

In some embodiments, a cleaning operation is performed on the first SiGe layer 2 before forming the second layer 3. The cleaning operation includes wet cleaning using dilute HF (DHF) and/or buffered HF (BHF). An in-situ cleaning using a gas or plasma (NF₃ and/or NH₃) in a chamber for forming the second layer may be employed as the cleaning operation.

The second layer 3 is formed by, for example, chemical vapor deposition (CVD), physical vapor deposition (PVD) including sputtering, atomic layer deposition (ALD) or other suitable film formation methods.

After the second layer is formed, a thermal process, i.e., annealing, is performed to form an alloy layer of the SiGe:P first material and the metal material of the second layer 3.

When the metal material of the second layer 3 is Ti, for example, a Ti(SiGe)₂ layer 4 is formed.

The annealing operation is performed at a temperature from about 500° C. to about 1100° C. in some embodiments. In certain embodiments, the annealing is performed at a temperature in a range from about 700° C. to about 1000° C. for a time period from about 10 sec to about 200 sec. In other embodiments, the annealing is performed at a temperature in a range from about 800° C. to about 1100° C. for a time period from about 1 μsec to about 1 sec. In other embodiments, the annealing period is in the millisecond range, for example, in a range from about 1 msec to about 100 msec. The annealing operation is performed in an inert gas ambient.

The thickness of the silicide-germanide (alloy) layer 4 is in a range from about 1 nm to about 10 nm in some embodiments, and is in a range from about 3 nm to about 5 nm in other embodiments.

By the annealing operation, the first SiGe:P layer 2 is substantially completely consumed to form the alloy layer 4 in some embodiments. In other embodiments, only a part of the first SiGe:P layer 2 is consumed to form the alloy layer 4 and the lower layer of the first SiGe:P layer 2 remains between the alloy layer 4 and the substrate layer 1.

By using a SiGe:P layer when forming an alloy layer of Ti, a Schottky barrier height (SBH) between the n-type SiP layer and the TiSiGe layer can be reduced, thereby reducing the contact resistivity by about 70% compared with TiSi (titanium silicide).

FIGS. 2-16 show exemplary cross sectional views of various stages for manufacturing a Fin FET device according to one embodiment of the present disclosure. It is understood that additional operations can be provided before, during, and after the processes shown by FIGS. 2-16, and some of the operations described below can be replaced or eliminated, for additional embodiments of the method. The order of the operations/processes may be interchangeable. Further, the configurations, structures, operations and/or materials used for FIGS. 1A-IC may be applied to the manufacturing processes shown by FIGS. 2-16, and the detailed description may be omitted.

To fabricate fin structures for the Fin FET device, a mask layer 15 is formed over a substrate 10. The mask layer 15 is formed by, for example, a thermal oxidation process and/or a chemical vapor deposition (CVD) process. The substrate 10 is, for example, a p-type silicon or germanium substrate with an impurity concentration in a range from about 1×10¹⁵ cm⁻³ to about 1×10¹⁶ cm⁻³. In other embodiments, the substrate is an n-type silicon or germanium substrate with an impurity concentration in a range from about 1×10¹⁵ cm⁻³ to about 1×10¹⁶ cm⁻³.

Alternatively, the substrate 10 may comprise another elementary semiconductor, such as germanium; a compound semiconductor including Group IV-IV compound semiconductors such as SiC and SiGe, Group III-V compound semiconductors such as GaAs, GaP, GaN, InP, InAs, InSb, GaAsP, AlGaN, AlInAs, AlGaAs, GaInAs, GaInP, and/or GaInAsP; or combinations thereof. In one embodiment, the substrate 10 is a silicon layer of an SOI (silicon-on insulator) substrate. Amorphous substrates, such as amorphous Si or amorphous SiC, or insulating material, such as silicon oxide may also be used as the substrate 10. The substrate 10 may include various regions that have been suitably doped with impurities (e.g., p-type or n-type conductivity).

The mask layer 15 includes, for example, a pad oxide (e.g., silicon oxide) layer 15A and a silicon nitride mask layer 15B in some embodiments.

The pad oxide layer 15A may be formed by using thermal oxidation or a CVD process. The silicon nitride mask layer 15B may be formed by a physical vapor deposition (PVD), such as a sputtering method, a CVD, plasma-enhanced chemical vapor deposition (PECVD), an atmospheric pressure chemical vapor deposition (APCVD), a low-pressure CVD (LPCVD), a high density plasma CVD (HDPCVD), an atomic layer deposition (ALD), and/or other processes.

The thickness of the pad oxide layer 15A is in a range from about 2 nm to about 15 nm and the thickness of the silicon nitride mask layer 15B is in a range from about 2 nm to about 50 nm in some embodiments. A mask pattern is further formed over the mask layer. The mask pattern is, for example, a resist pattern formed by lithography operations.

By using the mask pattern as an etching mask, a hard mask pattern 15 of the pad oxide layer and the silicon nitride mask layer is formed, as shown in FIG. 2.

Then, as shown in FIG. 3, by using the hard mask pattern 15 as an etching mask, the substrate 10 is patterned into fin structures 20 by trench etching using a dry etching method and/or a wet etching method.

In FIG. 3, three fin structures 20 are disposed over the substrate 10. However, the number of the fin structures is not limited to three. The numbers may be as small as one or more than three. In addition, one or more dummy fin structures may be disposed adjacent both sides of the fin structure 20 to improve pattern fidelity in patterning processes.

The fin structure 20 may be made of the same material as the substrate 10 and may continuously extend from the substrate 10. In this embodiment, the fin structure is made of Si. The silicon layer of the fin structure 20 may be intrinsic, or appropriately doped with an n-type impurity or a p-type impurity.

The width W1 of the fin structure 20 is in a range from about 5 nm to about 40 nm in some embodiments, and is in a range from about 7 nm to about 12 nm in other embodiments. The space S1 between two fin structures is in a range from about 10 nm to about 50 nm in some embodiments. The height (along the Z direction) of the fin structure 20 above the substrate 10 is in a range from about 100 nm to about 300 nm in some embodiments, and is in a range from about 50 nm to 100 nm in other embodiments.

The lower part of the fin structure 20 under the gate structure 40 (see, FIGS. 6B and 7A) may be referred to as a well region, and the upper part of the fin structure 20 may be referred to as a channel region. Under the gate structure 40, the well region is embedded in the isolation insulating layer 30 (see, FIG. FIGS. 6B and 7A), and the channel region protrudes from the isolation insulating layer 30. A lower part of the channel region may also be embedded in the isolation insulating layer 30 to a depth of about 1 nm to about 5 nm.

The height of the well region is in a range from about 60 nm to 100 nm in some embodiments, and the height of the channel region is in a range from about 40 nm to 60 nm, and is in a range from about 38 nm to about 55 nm in other embodiments.

In some embodiments, after the fin structures 20 are formed, the substrate 10 is further etched to form a mesa shape 10M, as shown in FIG. 4. In other embodiments, the mesa shape 10M is first formed, and then the fin structures 20 are formed. The mesa shape is not formed in certain other embodiments.

After the fin structures 20 and the mesa shape 10M are formed, the isolation insulating layer 30 is formed in spaces between the fin structures and/or a space between one fin structure and another element formed over the substrate 10. The isolation insulating layer 30 may also be called a “shallow-trench-isolation (STI)” layer. The insulating material for the isolation insulating layer 30 may include one or more layers of silicon oxide, silicon nitride, silicon oxynitride (SiON), SiOCN, fluorine-doped silicate glass (FSG), or a low-k dielectric material. The isolation insulating layer is formed by LPCVD (low pressure chemical vapor deposition), plasma-CVD or flowable CVD. In the flowable CVD, flowable dielectric materials instead of silicon oxide may be deposited. Flowable dielectric materials, as their name suggest, can “flow” during deposition to fill gaps or spaces with a high aspect ratio. Usually, various chemistries are added to silicon-containing precursors to allow the deposited film to flow. In some embodiments, nitrogen hydride bonds are added. Examples of flowable dielectric precursors, particularly flowable silicon oxide precursors, include a silicate, a siloxane, a methyl silsesquioxane (MSQ), a hydrogen silsesquioxane (HSQ), an MSQ/HSQ, a perhydrosilazane (TCPS), a perhydro-polysilazane (PSZ), a tetraethyl orthosilicate (TEOS), or a silyl-amine, such as trisilylamine (TSA). These flowable silicon oxide materials are formed in a multiple-operation process. After the flowable film is deposited, it is cured and then annealed to remove un-desired element(s) to form silicon oxide. When the un-desired element(s) is removed, the flowable film densifies and shrinks. In some embodiments, multiple anneal processes are conducted. The flowable film is cured and annealed more than once. The flowable film may be doped with boron and/or phosphorous.

The insulating layer 30 is first formed in a thick layer so that the fin structures are embedded in the thick layer, and the thick layer is recessed so as to expose the upper portions of the fin structures 20, as shown in FIG. 5. The height H1 of the fin structures from the upper surface of the isolation insulating layer 30 is in a range from about 20 nm to about 100 nm in some embodiments, and is in a range from about 30 nm to about 50 nm in other embodiments. After or before recessing the isolation insulating layer 30, a thermal process, for example, an anneal process, may be performed to improve the quality of the isolation insulating layer 30. In certain embodiments, the thermal process is performed by using rapid thermal annealing (RTA) at a temperature in a range from about 900° C. to about 1050° C. for about 1.5 seconds to about 10 seconds in an inert gas ambient, such as an N₂, Ar or He ambient.

After the insulating layer 30 is formed, a gate structure 40 is formed over the fin structures 20, as shown in FIGS. 6A and 6B. FIG. 6A is a plan view (view from the above) and FIG. 6B is an exemplary perspective view. FIG. 7A is an exemplary cross sectional view along the line a-a of FIGS. 6A and 6B and FIG. 7B is an exemplary cross sectional view along the line b-b of FIGS. 6A and 6B. FIGS. 8-11 and 13-16 are also exemplary cross sectional views corresponding to the line b-b of FIGS. 6A and 6B. FIG. 12A is an exemplary cross sectional view corresponding to the line c-c of FIGS. 6A and 6B, and FIG. 12B is an exemplary cross sectional view corresponding to the line b-b of FIGS. 6A and 6B.

As shown in FIGS. 6A and 6B the gate structure 40 extends in the X direction, while the fin structures 20 extend in the Y direction.

To fabricate the gate structure 40, a dielectric layer and a poly silicon layer are formed over the isolation insulating layer 30 and the exposed fin structures 20, and then patterning operations are performed so as to obtain gate structures including a gate pattern 44 made of poly silicon and a dielectric layer 42. In some embodiments, the polysilicon layer is patterned by using a hard mask and the hard mask remains on the gate pattern (gate electrode layer) 44 as a cap insulating layer 46. The hard mask (cap insulating layer 46) includes one or more layers of insulating material. The cap insulating layer 46 includes a silicon nitride layer formed over a silicon oxide layer in some embodiments. In other embodiments, the cap insulating layer 46 includes a silicon oxide layer formed over a silicon nitride layer. The insulating material for the cap insulating layer 46 may be formed by CVD, PVD, ALD, e-beam evaporation, or other suitable process.

In some embodiments, the dielectric layer 42 may include one or more layers of silicon oxide, silicon nitride, silicon oxy-nitride, or high-k dielectrics. In some embodiments, a thickness of the dielectric layer 42 is in a range from about 2 nm to about 20 nm, and in a range from about 2 nm to about 10 nm in other embodiments. The height H2 of the gate structures (see, FIG. 7A) is in a range from about 50 nm to about 400 nm in some embodiments, and is in a range from about 100 nm to 200 nm in other embodiments.

In some embodiments, a gate replacement technology is employed. In such a case, the gate pattern 44 and the dielectric layer 42 are a dummy gate electrode and a dummy gate dielectric layer, respectively, which are subsequently removed. If a gate-first technology is employed, the gate pattern 44 and the dielectric layer 42 are used as a gate electrode and a gate dielectric layer.

Further, gate sidewall spacers 48 are formed on both sidewalls of the gate pattern. The sidewall spacers 48 include one or more layers of insulating material, such as SiO₂, SiN, SiON, SiOCN or SiCN, which are formed by CVD, PVD, ALD, e-beam evaporation, or other suitable process. A low-k dielectric material may be used as the sidewall spacers. The sidewall spacers 48 are formed by forming a blanket layer of insulating material and performing anisotropic etching. In one embodiment, the sidewall spacer layers are made of silicon nitride based material, such as SiN, SiON, SiOCN or SiCN.

Then, as shown in FIG. 8, a fin mask layer 50 is formed over the fin structures 20. The fin mask layer 50 is made of dielectric material including silicon nitride based material, such as SiN, SiON, SiOCN or SiCN. In one embodiment, SiN is used as the fin mask layer 50. The fin mask layer 50 is formed by CVD, PVD, ALD, e-beam evaporation, or other suitable process.

The thickness of the fin mask layer 50 is in a range from about 3 nm to about 10 nm in some embodiments. The variation of the thickness is within about ±2 nm in certain embodiments.

In some embodiments, the fin mask layer 50 and the sidewall spacers 48 for the gate structure are separately formed. In other embodiments, the same blanket layer is used for the fin mask layer 50 and the sidewall spacers 48.

After forming the fin mask layer 50, the upper portion of the fin structures 20 are recessed and a part of the fin mask layer 50 disposed on side surfaces and the top surface of the fin structures protruding from the isolation insulating layer are removed by a dry etching and/or a wet etching operation. The upper portion of the fin structures 20 are recessed (etched) down to the level equal to or below the upper surface of the upper surface isolation insulating layer 30, as shown in FIG. 9.

Then, as shown in FIG. 10, an epitaxial source/drain structure 60 is formed over the recessed fin structures 20. In this disclosure, a source and a drain are interchangeably used, and a source/drain (or S/D) refers to one of or both of a source and a drain.

The epitaxial source/drain structure 60 is made of one or more layers of semiconductor material having a different lattice constant than the fin structures 20 (channel regions). When the fin structures are made of Si, the epitaxial source/drain structure 60 includes SiP, SiC or SiCP for an n-channel Fin FET. In this embodiment, SiP is used. An amount of P in the SiP layer is in a range from about 1×10²⁰ cm⁻³ to about 5×10²¹ cm⁻³ in some embodiments. In certain embodiments, the SiP layer includes two or more SiP layers with different P amounts.

Further, in some embodiments, the epitaxial source/drain structure 60 includes two or more epitaxially grown semiconductor layers. In certain embodiments, the epitaxial source/drain structure 60 includes a first SiP layer 62 formed on the recessed fin structure and a second SiP layer 64 formed on the first SiP layer 62 (see, FIGS. 12A and 12B).

An amount of phosphorous in the first SiP layer 62 is smaller than an amount of phosphorous in the second SiP layer 64. In some embodiments, the amount of phosphorous in the first SiP layer 62 is in a range from about 2×10²⁰ cm⁻³ to about 7×10²⁰ cm⁻³, and the amount of phosphorous in the second SiP layer 64 is in a range from about 3×10²⁰ cm⁻³ to about 4×10²¹ cm⁻³.

The epitaxial source/drain structure 60 is epitaxially formed over the upper portions of the recessed fin structures, and thus has a crystalline structure. Due to the crystal orientation of the substrate formed into the fin structures 20 (e.g., (100) plane), the epitaxial source/drain structure 60 grows laterally and has a diamond-like shape.

The source/drain epitaxial layer 60 may be grown at a temperature of about 600 to 800° C. under a pressure of about 80 to 150 Torr, by using a Si containing gas such as SiH₄, Si₂H₆ or SiCl₂H₂, and/or a dopant gas, such as PH₃.

After forming the epitaxial source/drain structure 60, a Si_(1-x)Ge_(x) layer 65 doped with phosphorous (P) (SiGe:P) is formed by an epitaxial deposition process over the source/drain epitaxial layer 60, as shown in FIG. 11. The fraction x of Ge in the SiGe:P 65 is in a range from about 0.25 to about 0.50 in some embodiments, and is in a range from about 0.30 to about 0.40 in other embodiments. An amount of phosphorous in the SiGe:P layer 65 is in a range from about 1×10²⁰ cm⁻³ to about 5×10²¹ cm⁻³ in some embodiments, and in in a range from about 5×10²⁰ cm⁻³ to about 1×10²¹ cm⁻³ in other embodiments.

FIG. 12A shows an exemplary cross sectional view corresponding to the line c-c of FIGS. 6A and 6B and FIG. 12B is an exemplary cross sectional view corresponding to the line b-b of FIGS. 6A and 6B. As shown in FIG. 12A, the lower part of the epitaxial source/drain structure is disposed below the upper surface of the isolation insulating layer 30. A depth D1 of the first SiP layer 62 from the interface between the epitaxial source/drain structure 60 and the SiGe:P layer 65 is in a range from about 40 nm to about 70 nm in some embodiments. A depth D2 of the second SiP layer 64 from the interface between the epitaxial source/drain structure 60 and the SiGe:P layer 65 is in a range from about 30 nm to about 60 nm in some embodiments. The depth (thickness) D3 of the SiGe:P layer 65 is in a range about 1 nm to about 20 nm in some embodiments, and is in a range from about 5 nm to about 10 nm in other embodiments. The distance D4 between the gate electrode 44 and the epitaxial source/drain structure 60 measured at the level of the upper surface of the isolation insulating layer 30 is in a range from about 2 nm to about 10 nm in some embodiments. The distance D5 between the gate electrode 44 and the epitaxial source/drain structure 60 measured at the level of the bottom 22 of the fin structure 20 is in a range from about 2 nm to about 15 nm in some embodiments.

In FIG. 11, the epitaxial source/drain structures of adjacent fin structures are separated from each other. In other embodiments, two or more epitaxial source/drain structures of adjacent fin structures are merged as shown in FIG. 12B. In such a case, the epitaxial source/drain structures 60 (the second SiP layers 64) are merged and the SiGe:P layer 65 is formed over the merged epitaxial source/drain structures. When two epitaxial layers are merged, the width L1 of the merged SiGe:P layer 65 is in a range from 60 nm to about 80 nm and the width L2 of the merged SiP layers 64 is in a range from about 45 nm to about 60 nm, in some embodiments. When the two epitaxial layers are not merged (a single fin), the outer most width of the SiGe:P layer 65 is in a range from about 30 nm to about 40 nm in some embodiments.

Next, as shown in FIG. 13, a metal layer 70 is formed over the SiGe:P layer 65. The metal material for the metal layer 70 includes one of Ti, Co, Ni, W or Ta. In one embodiment, Ti is used for the metal layer 70. The thickness of the metal layer 70 is in a range from about 1 nm to about 15 nm in some embodiments, and is in a range from about 3 nm to about 10 nm in other embodiments.

After the metal layer 70 is formed, a thermal operation (annealing) is performed so as to form an alloy layer 75 containing Si, Ge and Ti, for example, a Ti(SiGe)₂ layer is formed, as shown in FIG. 14.

The annealing operation is performed at a temperature from about 500° C. to about 1100° C. in some embodiments. In certain embodiments, the annealing is performed at a temperature in a range from about 700° C. to about 1000° C. for a time period from about 10 sec to about 200 sec. In other embodiments, the annealing is performed at a temperature in a range from about 800° C. to about 1100° C. for a time period from about 1 μsec to about 1 sec. In other embodiments, the annealing period is in the millisecond range, for example, in a range from about 1 msec to about 100 msec. The annealing operation is performed in an inert gas ambient.

The thickness of the silicide-germanide (alloy) layer 75 is in a range from about 1 nm to about 10 nm in some embodiments, and is in a range from about 3 nm to about 5 nm in other embodiments.

By the annealing operation, the SiGe:P layer 65 is substantially completely consumed to form the alloy layer 75 in some embodiments. In other embodiments, only a part of the SiGe:P layer 65 is consumed to form the alloy layer 75 and the lower layer of the SiGe:P layer 65 remains between the alloy layer 75 and the epitaxial source/drain structure 60.

Further, in some embodiments, the Ti layer 70 is not completely consumed, and a part of the Ti layer 70 remains over the alloy layer 75. In such a case, the remaining Ti layer 70 is removed by an appropriate etching operation.

Then, as shown in FIG. 15, an insulating layer 80, which functions as an etching stop layer in subsequent contact etching, and a first interlayer dielectric (ILD) layer 90 are formed. The first ILD layer 90 may include two or more ILD layers.

The insulating layer 80 includes one or more layers of insulating material, such as SiN, SiON, SiOCN or SiCN. In one embodiment, SiN is used as the first insulating layer 80. The first ILD layer 90 includes one or more layers of insulating material, such as SiO₂, SiON or SiOC, or a low-k dielectric material. In one embodiment, SiO₂ is used as the first ILD layer 90.

Then, by using a lithography operation and an etching operation, a contact hole is formed in the insulating layer 80 and the first ILD layer 90, and the contact hole is filled with a conductive material, thereby forming a contact plug 100. The contact plug 100 may include a single layer or multiple layers of any suitable metal such as Co, W, Ti, Ta, Cu, Al and/or Ni and/or nitride thereof.

In some embodiments, a metal gate structure (not shown) is formed by a gate replacement technology. After forming the alloy layer 75, and before forming the contact hole, the dummy gate structures (dummy gate electrode layer 44 and dummy gate dielectric layer 42) are removed and replaced with a metal gate structures (metal gate electrode and gate dielectric layer).

A dielectric layer is formed over the dummy gate structures and a planarization operation, such as a chemical mechanical polishing (CMP) process or an etch-back process, is performed to expose the upper surface of the dummy gate electrode layer 44. Then, the dummy gate electrode layer 44 and the dummy gate dielectric layer 42 are removed, by appropriate etching processes, respectively, to form a gate opening. Metal gate structures including a gate dielectric layer and metal gate electrode are formed in the gate openings.

The gate dielectric layer may be formed over an interface layer (not shown) disposed over the channel layer of the fin structures 20. The interface layer may include silicon oxide or germanium oxide with a thickness of 0.2 nm to 1.5 nm in some embodiments. In other embodiments, the thickness of the interface layer is in a range about 0.5 nm to about 1.0 nm.

The gate dielectric layer includes one or more layers of dielectric materials, such as silicon oxide, silicon nitride, or high-k dielectric material, other suitable dielectric material, and/or combinations thereof. Examples ofhigh-k dielectric material include HfO₂, HfSiO, HfSiON, HfTaO, HfTiO, HfZrO, zirconium oxide, aluminum oxide, titanium oxide, hafnium dioxide-alumina (HfO₂—Al₂O₃) alloy, other suitable high-k dielectric materials, and/or combinations thereof. The gate dielectric layer is formed by, for example, chemical vapor deposition (CVD), physical vapor deposition (PVD), atomic layer deposition (ALD), high density plasma CVD (HDPCVD), or other suitable methods, and/or combinations thereof. The thickness of the gate dielectric layer is in a range from about 1 nm to about 10 nm in some embodiments, and may be in a range from about 2 nm to about 7 nm in other embodiments.

The metal gate electrode is formed over the gate dielectric layer. The metal gate electrode includes one or more layers of any suitable metal material, such as aluminum, copper, titanium, tantalum, cobalt, molybdenum, tantalum nitride, nickel silicide, cobalt silicide, TiN, WN, TiAl, TiAIN, TaCN, TaC, TaSiN, metal alloys, other suitable materials, and/or combinations thereof.

In certain embodiments of the present disclosure, one or more work function adjustment layers (not shown) may be interposed between the gate dielectric layer and the metal gate electrode. The work function adjustment layer is made of a conductive material such as a single layer of TiN, TaN, TaAlC, TiC, TaC, Co, Al, TiAl, HfTi, TiSi, TaSi or TiAlC, or a multilayer of two or more of these materials. For the n-channel Fin FET, one or more of TaN, TaAlC, TiN, TiC, Co, TiAl, HfTi, TiSi and TaSi is used as the work function adjustment layer, and for the p-channel Fin FET, one or more of TiAIC, Al, TiAl, TaN, TaAlC, TiN, TiC and Co is used as the work function adjustment layer.

After depositing appropriate materials for the metal gate structures, planarization operations, such as CMP, are performed.

After forming the contact plug 100, further CMOS processes are performed to form various features such as additional interlayer dielectric layer, contacts/vias, interconnect metal layers, and passivation layers, etc.

FIGS. 17-21 show exemplary cross sectional views of various stages for manufacturing a Fin FET device according to another embodiment of the present disclosure. It is understood that additional operations can be provided before, during, and after processes shown by FIGS. 17-21, and some of the operations described below can be replaced or eliminated, for additional embodiments of the method. The order of the operations/processes may be interchangeable. Further, the configurations, structures, operations and/or materials used for FIGS. 1A-1C and FIGS. 2-16 may be applied to the manufacturing processes shown by FIGS. 17-21, and the detailed description may be omitted.

In this embodiment, the alloy layer of SiGe:P and Ti is formed after the contact hole is opened.

After the SiGe:P layer 65 is formed as shown in FIG. 11, an insulating layer 80′, similar to the insulating layer 80, which functions as an etching stop layer in the subsequent contact etching, is formed. Then, a first ILD layer 90′, similar to the first ILD layer 90, is formed, as shown in FIG. 17.

Then, by using a lithography operation and an etching operation, a contact hole 95 is formed in the insulating layer 80′ and the first ILD layer 90′, as shown in FIG. 18.

Then, as shown in FIG. 19, a metal layer 70′, such as a Ti layer, is formed over the SiGe:P layer 65, similar to FIG. 13. As shown in FIG. 19, the Ti layer 70′ is also formed on the walls of the contact hole 95 and the upper surface of the first ILD layer 90′.

Similar to FIG. 14, a thermal process is performed so as to form an alloy layer 75′ of Si, Ge and Ti, as shown in FIG. 20. In some embodiments, the Ti layer 70′ is not completely consumed, and a part of the Ti layer 70′ remains over the alloy layer 75′. In such a case, the remaining Ti layer 70′ is removed by an appropriate etching operation. In other embodiments, the remaining Ti layer 70′ is not removed.

Then, as shown in FIG. 21, a conductive material is formed in the contact hole 95, so as to form a contact plug 100′. The conductive material is deposited in the contact hole 95 and the and over the first ILD layer 90, and then a CMP process is performed to obtain the contact plug 100′. Any unconsumed Ti layer 70′ remaining on the upper surface of the first ILD layer 90 is removed by the CMP process.

After forming the contact plug 100′, further CMOS processes are performed to form various features such as additional interlayer dielectric layers, contacts/vias, interconnect metal layers, and passivation layers, etc.

In the present disclosure, since a SiGe:P layer is formed between a Ti layer and a semiconductor layer (e.g., SiP layer) when forming an alloy layer for the source/drain structure, a Schottky barrier height (SBH) between the n-type semiconductor layer (SiP) layer and the TiSiGe layer can be reduced, thereby reducing the contact resistivity of the source/drain structure by about 70% compared with a TiSi layer.

It will be understood that not all advantages have been necessarily discussed herein, no particular advantage is required for all embodiments or examples, and other embodiments or examples may offer different advantages.

In accordance with one aspect of the present disclosure, in a method of manufacturing a semiconductor device, a first layer containing a Si_(1-x)Ge_(x) layer doped with phosphorous is formed over an n-type semiconductor layer, a metal layer containing a metal material is formed over the first layer, and a thermal process is performed to form an alloy layer including Si, Ge and the metal material.

In accordance with another aspect of the present disclosure, in a method of manufacturing a semiconductor device including a fin field effect transistor (FinFET), a fin structure is formed over a substrate. The fin structure extends in a first direction in plan view. An isolation insulating layer is formed over the substrate so that a lower portion of the fin structure is embedded in the isolation insulating layer and an upper portion of the fin structure is exposed from the isolation insulating layer. A gate structure is formed over a part of the fin structure. The gate structure includes a gate electrode and a gate dielectric layer, and extends in a second direction crossing the first direction in plan view. An upper portion of the fin structure not covered by the gate structure is recessed. An epitaxial structure is formed over the recessed fin structure. A silicide layer is formed over at least a part of the epitaxial structure. The epitaxial structure includes an n-type semiconductor layer formed over the recessed fin structure and a Si_(1-x)Ge_(x) layer doped with phosphorous formed over the n-type semiconductor layer. In the forming the silicide layer, a Ti layer is formed over the Si_(1-x)Ge_(x) layer, and a thermal process is performed to form an alloy of Ti, Si and Ge. The n-type semiconductor layer is a SiP layer.

In accordance with another aspect of the present disclosure, an n-channel semiconductor field effect transistor comprises an isolation insulating layer, a fin structure, a gate structure and a source/drain structure. The isolation insulating layer is disposed over a substrate. The fin structure is disposed over the substrate, and extends in a first direction in plan view. An upper portion of the fin structure is exposed from the isolation insulating layer. The gate structure is disposed over a part of the fin structure, and extends in a second direction crossing the first direction. The source/drain structure is disposed on the upper portion of the fin structure, which is not covered by the gate structure and exposed from the isolation insulating layer. The source/drain structure includes a SiP layer, and an upper portion of the source/drain structure includes an alloy layer of Si, Ge and Ti.

The foregoing outlines features of several embodiments or examples so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments or examples introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure. 

What is claimed is:
 1. A semiconductor device, comprising: an isolation insulating layer disposed over a substrate; a fin structure disposed over the substrate, and extending in a first direction in plan view, an upper portion of the fin structure being exposed from the isolation insulating layer; a gate structure disposed over a part of the fin structure, the gate structure extending in a second direction crossing the first direction; and a source/drain structure formed on the upper portion of the fin structure, which is not covered by the gate structure and exposed from the isolation insulating layer, wherein: the semiconductor device is an n-channel semiconductor field effect transistor, the source/drain structure includes a SiP layer, and an upper portion of the source/drain structure includes an alloy layer of Si, Ge and Ti.
 2. The semiconductor device of claim 1, wherein an amount of phosphorous in the SiP layer is in a range from 1×10²⁰ cm⁻³ to 5×10²¹ cm⁻³.
 3. The semiconductor device of claim 1, wherein the alloy layer is in contact with the SiP layer.
 4. The semiconductor device of claim 1, wherein the SiP layer includes a first SiP layer and a second SiP layer having different phosphorous concentration from each other.
 5. The semiconductor device of claim 4, wherein an amount of phosphorous in the first SiP layer is smaller than an amount of phosphorous in the second SiP layer.
 6. The semiconductor device of claim 5, wherein the amount of phosphorous in the first SiP layer is in a range from 2×10²⁰ cm⁻³ to 7×10²⁰ cm⁻³, and the amount of phosphorous in the second SiP layer is in a range from 3×10²⁰ cm⁻³ to 4×10²¹ cm⁻³.
 7. A semiconductor device including an n-type FET, the n-type FET comprising: an isolation insulating layer disposed over a substrate; a fin structure disposed over the substrate, and extending in a first direction in plan view, an upper portion of the fin structure being exposed from the isolation insulating layer; and a source/drain structure formed on the upper portion of the fin structure, wherein: the source/drain structure includes a SiP layer and a SiGe layer disposed over the SiP layer and an alloy layer of Si, Ge and Ti disposed over the SiGe layer.
 8. The semiconductor device of claim 7, wherein the SiP layer includes a first SiP layer and a second SiP layer having different phosphorous concentration from each other.
 9. The semiconductor device of claim 8, wherein an amount of phosphorous in the first SiP layer is smaller than an amount of phosphorous in the second SiP layer.
 10. The semiconductor device of claim 9, wherein the amount of phosphorous in the first SiP layer is in a range from 2×10²⁰ cm⁻³ to 7×10²⁰ cm⁻³, and the amount of phosphorous in the second SiP layer is in a range from 3×10²⁰ cm⁻³ to 4×10²¹ cm⁻³.
 11. The semiconductor device of claim 7, wherein the SiGe layer is a Si_(1-x)Ge_(x) layer, where x is in a range from 0.25 to 0.5.
 12. The semiconductor device of claim 11, wherein the SiGe layer further contains phosphorous.
 13. The semiconductor device of claim 12, wherein an amount of phosphorus in the Si_(1-x)Ge_(x) layer is in a range from 1×10²⁰ cm⁻³ to 5×10²¹ cm⁻³.
 14. A semiconductor device including an n-type FET, the n-type FET comprising: an isolation insulating layer disposed over a substrate; a fin structure disposed over the substrate, and extending in a first direction in plan view, an upper portion of the fin structure being exposed from the isolation insulating layer; a source/drain structure formed on the upper portion of the fin structure; and a source/drain contact disposed over the source/drain structure, wherein: the source/drain structure includes a SiP layer, a layer containing Si and Ge is formed over the SiP layer, an upper part of the layer is an alloy layer of Si, Ge and Ti and is in contact with the source/drain contact, and a lower part of the layer containing Si and Ge not in contact with the source/drain contact is a Si_(1-x)Ge_(x) layer without Ti.
 15. The semiconductor device of claim 14, wherein the SiP layer includes a first SiP layer and a second SiP layer having different phosphorous concentration from each other.
 16. The semiconductor device of claim 15, wherein an amount of phosphorous in the first SiP layer is smaller than an amount of phosphorous in the second SiP layer.
 17. The semiconductor device of claim 14, wherein the amount of phosphorous in the first SiP layer is in a range from 2×10²⁰ cm⁻³ to 7×10²⁰ cm⁻³, and the amount of phosphorous in the second SiP layer is in a range from 3×10²⁰ cm⁻³ to 4×10²¹ cm⁻³.
 18. The semiconductor device of claim 14, wherein x in the Si_(1-x)Ge_(x) layer is in a range from 0.25 to 0.5.
 19. The semiconductor device of claim 14, wherein the Si_(1-x)Ge_(x) layer further contains phosphorous, and an amount of phosphorus in the Si _(1-x)Ge_(x) layer is in a range from 1×10²⁰ cm⁻³ to 5×10²¹ cm⁻³. 